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To a 150 mL beaker were added 0.510 g of solid copper powder and 2.5 mL of a 15 M aqueous solution of nitric acid. Brown fumes were evolved, and 25 mL of water was then added to the blue solution formed. To the aqueous solution was added 3.010 g of solid sodium carbonate in small portions. Only after all of the excess hydrogen ion in the aqueous solution was consumed by reaction with added carbonate ion did carbonate ion precipitate copper (II) ion as copper (II) carbonate. The solid copper (II) carbonate was isolated by vacuum filtration and dried; 0.920 g of copper (II) carbonate was collected. The net ionic equations for the reactions which occurred are shown below.
Cu(s) + 4H+(aq) + 2NO3-(aq) ==> Cu2+(aq) + 2NO2(g) + 2H2O(l)
2H+(aq) + CO32-(aq) ==> H2O(l) + CO2(g)
Cu2+(aq) + CO32-(aq) ==> CuCO3(s)
Calculate the percent yield of copper (II) carbonate.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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