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Design a CSTR to provide pretreatment for an industrial wastewater that flows at a rate of 1,000 fpm with a phenol concentration of 200 mg/L. Phenol undergoes a first-order decay reaction in the CSTR with a rate constant, k=0.50 hr^(-1). The current industrial pretreatment permit limitation for phenol is 20 mg/L. The permit limitation may be changed, either higher or lower, in the future. 1. Determine the required CSTR volume, V (in gallons), and hydraulic residence time, in V/Q (hours), to comply with the current industrial pretreatment permit limitation for phenol. 2. Plot a graph with CSTR effluent phenol concentration in mg/L along the vertical axis as a function of CSTR hydraulic residence time in hours, on the horizontal axis for assessing the impact of changes in the permit limitation. Use a spreadsheet to perform the repetitive calculations and then use the spreadsheet's graphing tools to plot the graph. Comment on a type of "Law of Diminishing Returns" on effluent phenol concentration versus the V/Q that applies to CSTR design for first-order decay reactions.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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