Explain the reaction of iodide ion with hypochlorite ion

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The reaction of iodide ion with hypochlorite ion, OCI - (the active ingredient in a chlorine bleach, such as Chlorox), follows the equation OCI- + I- OI- + CI- It is a rapid reaction that gives the following rate data:

Initial Concentrations (mol L-) Rate of Formation of Cl- (mol L-1s-1)

[OCI-] [I-]    (mol L-1s-1)
1.6 x 10-3    1.6 x 10-3    1.75 x 104
7.6 x 10-3    1.6 x 10-3    8.31 x 104
1.6 x 10-3    9.6 x 10-3    1.05 x 105

What is the overall order of the reaction?

Reference no: EM13503396

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