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Consider the dimerization 2A to A2, with forward rate constant ka and backward rate constant kb. (a) derive the following expression for the relaxation time in terms of the total concentration of protein [A]tot = [A] + 2[A2]: (1/tau^2) = kb^2 + 8kakb[A]tot
(b) describe the computational procedures that lead to the determination of the rate constants ka and kb from measurements of tau for different values of [A]tot
(c) use the data provided below and the procedure you outlined in part b to calculate the rate constants ka and kb, and the equilibrium constant K for formation of hydrogen-bonded dimers of 2-pyridone
When a 4.25g sample of solid ammonium nitrate dissolves in 60.00g of water in another insulating calorimeter the temperature drops from 21.0450C to 16.8700C. What is the (delta)H for the dissolution
How much energy is required to evaporate 100.0 grams of water that is at 100.0 degrees Celsius?
How would you prepare 350mL of a single solution containing 150mM Tris, 5mM glucose, and 5 mM Nacl?
Explain the differences in values of the ligand field splittings (Delta = DeltaO or DeltaT for the cobalt complexes below): [Co(NH3)6]3+ ----> Delta = 22,900 cm-1, [Co(H20)6]3+ -----> Delta = 18,200 cm-1, [Co(NH3)6]2+ -----> Delta = 10,200 cm-1 [C..
2ch3oh3o2 gives 2co24h2o. calculate the heat of combustion of one mole of methanol under standard
what is the term for a substance that is capable of either accept or donate a proton in as which base reaction?
Consider the following species: Ca, Br1-, Fe2+ , Cu+, Co3+. Li+. List the oxidizing agents. List the reducing agents. (Some could be both.) Which is the best oxidizing agent
Enough water to make 2.00 L of solution is added to 25.00 mL of concentrated (18 M) sulfuric acid. What is the molarity of the resulting solution.
The haber process for production of ammonia proceeds via the following reaction: N2 +3H2 --> 2 NH3 What is the relationship between the rate of ammonia production and hydrogen consumption
which compartment (A or B) will increase in volume for each of the following pairs of solutions separated by a semipermiable membranes: a) A.20%(m/v) starch B.10%(m/v) starch. b) A.10%(m/v) albumin B.2%(m/v) albumin. c) A. .5%(m/v) sucrose B. 5%(m..
At 40°C, the vapor pressure of heptane is 92 torr. If a solution is made of naphthalene in heptane and has a vapor pressure of 82 torr, what is the mole fraction of naphthalene? Assume ideal solution behavior.
Illustrate this by showing the reaction of trans-p-anisalacetophenone with bromine and 2,4-dinitrophenylhydrazine to give the corresponding products
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