Explain the proton nmr spectrum of compound d

Assignment Help Chemistry
Reference no: EM13229557

Compound A (C11H16O) has a band in the IR spectrum at 3450 cm-1 (strong, broad) and does not react with pyridinium chlorochromate (PCC) in CH2Cl2. Compound A does react with HBr to give compound B (C11H15Br). Compound B reacts with potassium t-butoxide to give compound C (C11H14). Ozonolysis of C followed by treatment with Zn and water gives CH3CHO and compound D (C9H10O). The proton NMR spectrum of compound D is given below. Treatment of compound D with ethyl magnesium bromide yields A. Draw the structures of compounds A, B, C, and D. 1H NMR of D: ? 8.1-7.5, multiplet, 5H; 2.85, quartet, 2H; 1.30, triplet, 3H.

Reference no: EM13229557

Questions Cloud

State oxidized to an optically inactive dicarboxylic acid c : With aqueous H2CrO4, compound A was oxidized to an optically inactive dicarboxylic acid C, C6H10O4. Give structures for compounds A, B, and C; do not specify stereochemistry.
Design full-wave bridge rectifier circuit to deliver 10volts : Design a full-wave bridge rectifier circuit to deliver 10 volts de with less than 0.1 volt (pp) ripple into a load draWing up to 10mA. Choose the appropriate ac input voltage. assuming 0.6 volt diode drops.
Explain heating a with hydrazine in base gave hydrocarbon c : When optically active B was treated with CrO3 in pyridine, an optically inactive sample of A was obtained. Heating A with hydrazine in base gave hydrocarbon C, which, when heated with alkaline KMnO4, gave carboxylic acid D. Identify compounds A, B..
Explain causes of difference between the emitted radiation : Compare this spectral distribution with that of the radiation received on the surface of the earth at AM1.5. Briefly explain the causes of the difference between the emitted radiation of the core of the sun and the received radiation at the earth'..
Explain the proton nmr spectrum of compound d : Ozonolysis of C followed by treatment with Zn and water gives CH3CHO and compound D (C9H10O). The proton NMR spectrum of compound D is given below. Treatment of compound D with ethyl magnesium bromide yields A. Draw the structures of compounds A, ..
What are earnings as a percentage of the final retail price : In the electronics business, mark-up is in the order of 100% to 130% at each level of middleman. Let's say that it is 100%. Let's further say that your product passes through three levels of middleman, that your product is produced in accordance
Explain how to recover the increased design cost : a cost to produce, P, of $4.00. If we were able to reduce this to $3.55 through greater attention in the design, and if the cost to improve the design (in NRE) is $35,000, how many units must we sell to recover the increased design cost
Examine the role of advertising and promotion management : Examine the role of advertising and promotion management in contemporary marketing and develop an understanding of integrated marketing communications, including the coordination of the various promotional mix elements
Find the reflection coefficient at the load : A 75- ohm lossless transmission line is interfaced to a load impedance that consists of a series connected resistor of 30 ohm and a capacitor of 10 pF. At an operating frequency of 2 GHz and for a wavelength of 10 cm.

Reviews

Write a Review

Chemistry Questions & Answers

  State why is it important to put a pinhole in the aluminum

Why is it important to make sure all of your unknown has vaporized? Why is it important to put a pinhole in the aluminum "cap"?

  Calculate the energy in kj required to raise the temperature

The specific heat capacity of silver is 0.240 J/(g x degrees C). Calculate the energy (in kJ) required to raise the temperature of 263 g Ag from 273K to 278 K.

  Explain nickell chlorides solution in a lead container

Would it be safer to store a nickell (II) chlorides solution in a lead container or a chromium container?

  State what was the wavelength of the photon emitted

The atom then emits two photons: one of wavelength 1282.2 nm to reach an intermediate level and a second to return to the ground state. What was the wavelength of the second photon emitted?

  Determine specific heat capacity of this sample of carbon

The amount of energy needed to heat 2.00 g of carbon from 50.0°C to 80.0°C is 42.6 J. The specific heat capacity of this sample of carbon is ?

  Explain what is the final pressure in the flask

In a closed 1.00 L flask, 2.60 atm of CO reacts with 5.80 atm of O2 according to the equation below. Assuming that the temperature remains constant, what is the final pressure in the flask?

  Explain how would you expect the amino acids glycine

How would you expect the amino acids glycine, alanine, and phenylalanine to travel relative to each other on the silica plates using a mixture of chloroform/methanol/ammonia? Explain your answer.

  State sketch a titration curve for the titration

Sketch a titration curve for the titration of 100mL of 1.25x10^-2 M ascorbic acid with 1.00x10^-2 M NaOH, given that Ka= 8.0x 10^-5 and Ka2= 1.6x10^-12. How many equivalence points should the curve have and what color indicator(s) could be used?

  Creating structural formulas

Draw structural formulas for all of the structural isomers of C4H10, C5H12 and C3H7Cl.

  Explain and identify the functional group

identify the functional group; and 3) and discuss general key chemical properties of the chemical that a fire, environmental, health or safety personnel should know.

  Calculate the diameter of a rhodium atom

Rhodium has a density of 12.45 g/cm3. This metal crystallizes in a face-centered cubic unit cell. Calculate the diameter of a rhodium atom?

  Presuming that all ionic species are completely dissociated

solution of potassium sulfate. Assuming that all ionic species are completely dissociated, what is the osmotic pressure of the mixture in torr?

Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd