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In the spring of 1996 five tank cars containing propane (molar mass = 44.09 g/mol) derailed in Weyauwega, WI forcing evacuation of the town for over a week. Residents within a square mile of the accident site were unable to return to their homes for over two weeks.
(A) Assuming that each tank car had a capacity of 33,500 gal, knowing that the density of liquid propane at its boiling point (-44.5°C) is 0.5853 g/cm3, and assuming that the propane vaporized and warmed to 25°C, how many kJ of heat would be evolved if all the propane reacted explosively with oxygen in the air?Substance Hof
C3 H8(g) -103.8CO2(g) -393.5H2O (l) -285.8
(B) H for the explosive decomposition of TNT (C7H5N3O6) to water, nitrogen, carbon monoxide, and carbon is -1066.1 kJ/mol. How many kilotons (1 Ton=103 kg) of TNT would provide the amount of energy equivalent to that produced by the combustion of five tank cars of propane?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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