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Buckminsterfullerene is an allotrope of carbon in which the carbon atoms form spheres of 60 carbons each. In a pure compound the spheres pack in a cubic close packed array. The length of the side of the face-centered cubic cell formed by buckminsterfullerene is 142 pm.
a. Use this information to calculate the radius of the buckminsterfullerene molecule treated as a hard sphere.
b. The compound K3C60 is a superconductor at low temperatures. In this compound the K+ ions lie in the holes in the C60- face-centered cubic lattice. Considering the radius of the K+ ion and assuming that the radius of C60- is the same as for the C60 molecule, predict in what type of holes the K+ ions lie (tetrahedral, octahedral, or both) and indicate what percentages of these holes are filled.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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