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A sample of coal is completely burned in a 10.0 L cylinder at a constant pressure of 1.10 atm and a temperature of 1000 oC. The combustion reaction produces 2.3x104 J of heat energy. As the gaseous products expand they push against a piston which increases the cylinder volume to 55.0 L. After combustion the gases are allowed to reach equilibrium. A chemical analysis shows that there are 15.7 moles of O2 and 9.8 moles of CO2 in the cylinder at equilibrium. A second combustion experiment is carried out at a temperature of 1455 oC. Using the information above calculate the equilibrium constant you would expect to measure for the experiment carried out at the higher temperature.
Calculate the total concentration of lead dissolved ([Pb]total) in a solution saturated with PbI2(s) and containing dissolved I- with a concentration of [I-] = 0.294 M. The solubility of lead is governed by the reactions shown below.
Water, sodium hydroxide, and 1,6-hexanediamine are all potential nucleophiles. Yet, only 1,6-hexanediamine reacts with the adipoyl chloride. Offer an explanation as to why.
Draw a graph that shows the relative energy of the conformer as a function of the torsional angle. Make sure that you clearly label which conformer corresponds to which position on the graph
a calorimeter contains 34.0 ml of water at 13.5 circc. when 1.80 g of rm x a substance with a molar mass of 70.0 gmol
Illustrate (draw) the thermodynamic cycles for the acid dissociation of both HCl and HF. Classify each cycle as exergonic or endergonic. Do your calculated values agree with the observed strengths of each acid in water?
Determine after how many days will one-sixteenth of a given amount of radon-222 remain and Determine the values of Delta E and Delta H for the system?
If 200ml of 2.00M HCL solution is added to 400ml of 1.00M NaOH solution What molarity will the resulting solution NaCl have?
When 1 mol of a gas burns at constant pressure, it produces 2414J of heat and does 4kJ of work. 1. Identify \Delta E for the process. Express your answer using one significant figure.
In a Diels-Alder reaction between 1mL (12mmol) of cyclopentadiene and 1.393 g (12mmol) of maleic acid, How do you calculate the Theoretical Yield
In the first step of the trypsin mechanism, the side-chain oxygen of Ser 195 attacks the carbonyl carbon of the substrate. Use PyMOL and your model of the enzyme substrate complex to determine the distance between these two atoms.
A student heated a 4.901 g sample of hydrated iron chloride. After heating, the anhydrous iron chloride has a mass of 3.010 g. Calculate the percentage by mass of water in the hydrated compound.
what is the condensed structural formula for the product of the hydrogenation of 2-butene using a platinum catalyst
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