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An investigator is conducting kinetic experiments on a first-order reaction A?P for which the rate coefficient at 298 K is k0 = 0.001 s^-1. The activation energy for the reaction is found to be 40 kJ mol^-1. Assume that a simple Arrhenius expression gives the dependence of k upon temperature. The investigator runs the reaction in a container whose temperature is increased to 500 K. What is the change in the half-life time?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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