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Two blocks of the same metal and mass are at different initial temperatures T1 and T2. The blocks are brought into contact and come to a final temperature Tf. Assume the system is totally isolated from the surroundings and that the surroundings are at equilibrium. a. Your intuition probably tells you that for 2 identical blocks, Tf is the average of the initial temperatures, so that Tf = 1/2 (T1 + T2). Show that for a system of two blocks totally isolated from the surroundings that this is true. b. Show that the change in entropy is ?S = CP ln T1 + T2 ( )2 4T1 T2 c. How does this expression show that this process is spontaneous?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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