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For each of the following pairs of polymers, (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why.
a) Isotactic polystyrene that has a density of 1.12 g/cm3 and a weight-average molecular weight of 150,000 g/mol; syndiotactic polystyrene that has a density of 1.10g/cm3 and a weight-average molecular weight of 125,000 g/mol
b) Linear polyethylene that has a degree of polymerization of 5000; linear and isotactic polypropylene that has a degree of polymerization of 6500
c) Branched and isotactic polystyrene that has a degree of polymerization of 4000; linear and isotactic polypropylene that has a degree of polymerization of 7500
The reaction between ethyl iodide and hydroxide ion in ethanol (c2h5oh) solution, c2h5oh + oh --> c2h5oh + I, has an activation energy of 86.8 kj/mol and a frequency factor of 2.1 x 10^ 11
Which statement is true concerning the reaction... N(g) + N(g) = N2(g) + energy?
0.8 moles of acetic acid (weak acid) is added to 1.25 liters of water and the pH is adjusted to 5.8. what is the concentration of acetate ion
what is the mass in grams of 30.0 mL of the liquid propylene gylcol, a moisturizing agent for foods, which has a density 1.036 g/mL at 25 degree Celsius.
Explain the difference between exposure to radioactivity from a source external to the body versus a source that has been consumed and is therefore inside the body.
The solubility of silver phosphate in pure water and Na3PO4, Silver Phosphate, Ag3PO4, is an ionic compound with a solubility product constant Ksp of 206 x 10 ^ - 18.
A piece of the mineral zircon is found to contain a Pb-206:U-238 ratio of 0.213 g:1.00 g. Assuming all Pb-206 in the sample is attributable to decay of U-236
What is the pH of a sodium acetate solution prepared by adding 0.820 grams of sodium acetate to 100.0 ml of water at 25.0 oC? The Ka at 25.0 oC for acetic acid is 1.8 × 10-5.
the system achieves thermoequilibrium at atmospheric pressure. Assume no heat loss to the surroundings. What is the final temperature of the combined metal sheets?
A chemical firm was hired to monitor a nearby lake for possible mercury contamination. Several samples were taken at different locations around the lake, including water samples.
0.1 Mol L-1 of HC2H3O2 and 0.05 mol L-1 of Hno2 are added to the same container of water at 298 K. compute the final pH of this solution.
If 28.9 grams of trans-2-butene reacts with 14.2 grams of HCl to form 15.5 grams of chlorobutane, what is the percent yield?
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