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In Lab 9, students performed acid-base titrations. Redox reactions can also be used in titrations. An example is the titration of ascorbic acid (H2C6H6O6) in lemon juice using triiodide (I3-). A starch indicator will turn the solution blue-black at the endpoint. The half-reactions involved are shown below.
C6H6O6 + 2 H+ + 2 e- ? H2C6H6O6 +0.06 VI3- + 2 e- ? 3 I- +0.53 V
Use the data given below to determine the amount of ascorbic acid in lemon juice. (Note: The recommended daily allowance of ascorbic acid (Vitamin C) is 90 mg.)
Data Table P6: Titration of ascorbic acid in lemon juice with triiodideconcentration of I3- 0.0190 Mvolume lemon juice 93.05 mLmass lemon juice 94.72 gequivalence volume of I3- 16.26 mLmmol of I3- _____________?_________mmolmmol of H2C6H6O6 _______?_________mmolmass of H2C6H6O6 ________?________mg
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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