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pH = pKa + log [A-]/[HA] 1. What is the pH of a solution containing 0.042 M NaH2PO4 and 0.058 M Na2HPO4 ? The pKa of sodium phosphate is 6.86. 2. What is the pH of the sodium phosphate buffer described in problem #1 if 1 ml of 10M NaOH is added? What is the pH of 1 liter of water if 1ml of NaOH is added? How does this illustrate the importance of buffers? 3. What is the pH of a solution prepared by mixing 200 ml of 0.1 M HCl with 300 ml of 0.1 M sodium acetate and diluting the mixture to 1 L? The pKa of acetic acid is 4.76 4. Calculate the ratio of dihydrogen phosphate to hydrogen phosphate in the blood at pH 7.4. The Ka = 6.3 x 10 -8 5. For a weak acid with a pKa of 6.0 calculate the ratio of conjugate base to acid at a pH of 5.0.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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