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Your friend came to you for several questions regarding the volatility, bioaccumulation potential and toxicity of BTEX compounds commonly present in the light fraction of gasoline. You find the following data from a reference book (E. R. Weiner, 2000) and try to help him.
Chemicals Solubility (mg/L) Henry's Law constant (unitless) log KOWBenzene 1750 0.228 2.13Toluene 626 0.272 2.75Ethlybenzene 169 0.323 3.14o-xylene 178 0.213 3.13m-xylene 161 0.301 3.20p-xylene 185 0.314 3.17
(1) Write the chemical structure of each compound.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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