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Primary AlcoholsPrimary alcohols can be oxidized to aldehydes and carboxylic acids. Often it is difficult to stop at the aldehyde oxidation state. One method frequently used to accomplish this, for those that boil below about 100 degrees C, is to remove the product from the reaction mixture as it is formed. This method is based on the fact that aldehydes have a lower boiling point than their corresponding alcohols. Explain this difference in boiling point.
What products would you expect from the reaction of 1 mol of 1,3-butadiene and each of the following reagents? (If no reaction would occur, indicate that as well.)
Given that the density of the gas mixture =0.312 g/L at the pressure of 0.2 atm and temperature 500 Kelvin At equilibrium. Determine the value of Kc also express your answer in units of (mol/L)?
a sample of nitrogen gas occupies 1.55 l at 27.0c and 1.00atm. what will be the volume be at -100.0 C and the same pressure
To what volume should you dilute 130. mL of an 7.11 M CuCl2 solution so that 65.0 mL of the diluted solution contains 4.24 g CuCl2?
The air in an inflated balloon (defined as the system) warms over a toaster and absorbs 121 J of heat. As it expands, it does 70. kJ of work. What is the change in internal energy for the system.
0.60 g of hydrogen chloride HCl is dissolved in water to make 7.5 L of solution. What is the pH of the resulting hydrochloric acid solution.
Determine how many milligrams of H 2 O are present in sample If the freezing point of a 100.0g sample of 2-methyl-2-propanol =24.59C?
A 15.00 mL sample of unknown concentration of sulfuric acid is precititated with excess lead(II) nitrate and a precipitate of lead(II) sulfate is collected.
How long would it take for 1.50 mol of water at 100.0 0C to be converted completely into steam if heat were added at a constant rate of 19.0 J/s?
25.0 cm3 of a saturated solution of Ca(OH)2 required 21.0 cm3 of 0.0500 mol dm-3 HCl for complete neutralisation. Calculate the [OH-(aq)] and the [Ca2+(aq)] in the saturated solution.
Consider two DNA molecules: one 400 base pairs long, the other 800 base pairs long. Assuming that each is a rigid rod of diameter 25 Å, with a length of 3.4 Å per base pai.
Calculate E when 900.0 g of CH3OH(g) completely reacts at a constant temperature of 300 K and constant pressure of 0.95 atm. R = 8.314 J/mol*K and R = 0.08206 atm*L/mol*K
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