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Iron(II) chloride (melting point 677°C) and potassium chloride (melting point 776°C) form the compounds KFeCl3 and K2FeCl4 at elevated temperatures. KFeCl3 melts congruently at 380°C and K2FeCl4 melts incongruently at 399°C. Eutectics are formed with compositions x = 0.38 (melting point 351°C) and x = 0.54 (melting point 393°C), where x is the mole fraction of FeCl2. The KCl solubility curve intersects the K2FeCl4 curve at x = 0.34. Sketch the phase diagram. State the phases that are in equilibrium when a mixture of composition x = 0.36 is cooled from 400°Cto 300°C.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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