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In the experiments described in Problems 21.10 and 21.11 an inverse temperature dependence of the reaction rate was observed, the overall rate of reaction at 70 degrees C being approximately one-third that at 19 degrees C. Estimate the apparent activation energy and the activation energy of the rate-determining step given that the enthalpies of the two equilibria are both of the order of -14 kJ mol-1.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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