Explain inverse temperature dependence of the reaction

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In the experiments described in Problems 21.10 and 21.11 an inverse temperature dependence of the reaction rate was observed, the overall rate of reaction at 70 degrees C being approximately one-third that at 19 degrees C. Estimate the apparent activation energy and the activation energy of the rate-determining step given that the enthalpies of the two equilibria are both of the order of -14 kJ mol-1.

Reference no: EM13292583

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