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Write a stepwise mechanism using arrows to show movement of electrons for the reaction of 1-butyne with hydrogen bromide to produce 2,2-dibromobutane. CH3CH2CCH + 2HBr --------->CH3CH2CBr2CH3
Provide reasoning for the observed regioselectivity for addition of each mole of hydrogen bromide.
calcuate the number of moles of HCI and of NaOH present when mixing 50.0mL
A sealed container holds 1.00 mole of helium and 2.00 moles of nitrogen at 30.0°C. When the total pressure of the mixture is 666 mm Hg, what is the partial pressure of the nitrogen? Provide an answer correct to 2 significant figures in mmHg.
A new catalyst is being developed with the hope of generating ethylene by the oxidative dehydrogenation of ethane, reaction (1). Two side reactions accompany the main reaction;
In the standardization of NaOH, 38.76 mL of NaOH was required for 0.8169 g potassium acid phthalate. Estimate the accuracy we should expect in the molarity of the NaOH solution assuming the weighing error is ±0.1 mg
The flask was then shaken until the solution was uniform. A 20.0-rm mL sample of this glucose solution was diluted to 0.500 rm L. How many grams of glucose are in 100. rm mL of the final solution?
Draw the Lewis structure of nitramide with a single bond between the two nitrogen atoms and include formal charges. Are there any resonance structures? If so, please draw these too. Describe the hybridization of the nitrogen atoms.
Splitting patterns and integrations may be used more than once, or not at all, as needed. Likewise, some bins might remain blank. Note that peak heights are arbitrary and do not indicate proton integrations.
What is the molar concentration of a H3PO3 solution if 150.00 mL of the solution was required to neutralize 75.00 mL of NaOH whose concentration was 1.50 molar?
Naturally occuring chlorine has two isotopes, Cl-35, which has an atomic mass of 34.969 amu and Cl-37. If the average atomic mass of chlorine is 35.46 amu and its natural abundance is 75.53%,
Calculate the value of heat of vaporization for this liquid Calculate the normal boiling point of this liquid.
Steam at 3MPa and 300oC exits a boiler and goes into a high pressure turbine in which it is expanded to 300kPa. The steam is then sent back to the boiler (constant pressure heat exchanger) and reheated to 300oC.
Which of the following is NOT true about the thermodynamic standard state?
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