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1. How would you expect the amino acids glycine, alanine, and phenylalanine to travel relative to each other on the silica plates using a mixture of chloroform/methanol/ammonia? Explain your answer.
2.You spot a sample of an unknown pure compound on a TLC plate and elute it with hexane. It's Rf is 0.25. Would you expect its Rf to increase, decrease, or remain the same if you elute with acetone? Why?
aqueous solution of sucrose, C12H22O11(aq), which is used frequently in biological experiments. What is the value of x?
An aqueous solution of KI has a freezing point of -1.70 C and an osmotic pressure of 26.5 atm at 25.0 C. What is the density ?
calculate acidic and basic buffer capacity. How much of strong acid should be added to shift buffer pH one unit down, and how much of the strong base is needed to bring buffer pH one unit up?
Calculate the superhelical density of a 5000 bp plasmid DNA containing 25 positive supercoils (of B-form DNA).
Both anthracene and phenanthrene will undergo addition with Br2. Anthracene adds Br2 at the 9- and 10-position. Is this consistent with the MO(s) shown in the SHMO program?
A lead bullet is fired at a wooden plank. At what speed must bullet travel to melt on impact, if its initial temperature is 25oC and the heating of the plank is neglected.
How many grams of CaH2 are needed to generate 147 L of H2 gas if the pressure of is 824 torr at 295K ?
Greg Nard added an equivalent of 3,4-epoxy-4-methylcyclohexanol to an ether solution of methyl magnesium bromide and then added dilute hydrochloric acid.
Imagine a silica microsphere half of which is coated with a thin gold coating and having a trimethylammoniumpropanethiol molecule anchored to the gold.
A rigid cylinder with a movable piston contains a 2.0-liter sample of neon gas at STP. What is the volume of this sample when its temperature is increased to 30.°C while its pressure is decreased to 90. kilopascals.
Describe how you would make 4 liters of a 0.075 M phosphate buffer at pH of 7.15 without using a pH meter, if the only materials
An evaluation of R was performed, following the procedure. The barometric pressure was 736torr, the temperature was 295K, and the volume of hydrogen gas collected was 35.6mL. The calculated value of R was 82.1 atm K-1 mol-1. How many grams of magn..
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