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Calculate the overall energy change in kilojoules per mole for the formation of CaCL(s) from the elements. The following data are needed: (a) Eea for CL(g) = -348.6kj/mol. (b) Ei1 for Ca(g) = +589.8kj/mol. (c) Ei2 for Ca(g) = +1145kj/mol. Heat of sublimation for Ca(s) = +178.2kj/mol. Bond dissociation energy for Cl2(g) = +243kj/mol. Lattice energy for CaCL2(s) = +2258kj/mol. Lattice energy for CaCL(s) = +717kj/mol (estimated) (Use the data from the above to calculate an overall energy change for the formation of CaCL2(s) from the elements. Which is more likely to form, CaCL or CaCL2?)
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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