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1. Based on resonance structures for acrolein, do you expect the C=O stretch in acrolein to be of higher fundamental frequency or lower fundamental frequency than that of propionaldehyde?
2.Which do you think would have a higher carbonyl stretch frequency - hexachloroacetone or acetone - explain.
3.Different hybridizations give rise to different vibrational frequencies. Terminal alkynes have C-H stretching frequencies of about 3300 cm-1; alkene C-H stretching frequencies are around 3100 cm-1, and alkane C-H stretching frequencies are around 2900 cm-1. Explain these observations - how does ‘s'-character affect vibrational frequencies?
What kind of compound is 2,3-dihydroxypentane? From what precursor do you synthesize the kind of compound that 2,3-dihydroxypentane is?
Decribe the preparation of the 100mL of a 50 mM acetate buffer at pH 5.5 beginning iwth sodium acetate and 1M acetic acid
Calculate the entropy change that occurs when 3.5 moles of an ideal gas expands from 1.75 L at 20 degress Celsius to 8.46 L at .54 atm.
why does the color change from blue to green or yellow near the endpoint of titration when the indicator is bromocresol green
A zero-order reaction has a constant rate of 3.50×10-4 M/rm s. If after 65.0 seconds the concentration has dropped to 1.00×10-2 M, what was the initial concentration?
The standard free energy of the reaction represents the drive the reaction has under standard conditions to move toward equilibrium. Express the equilibrium constant numerically using three significant figures.
if you add .454g of nitroglycerine to 100g of benzene at 25C, the vapor pressure of the solution is 94.85mmHg. Calculate the molar mass of nitroglycerine.
If a diamond consisting of ten sextillion "randomly-selected" carbon atoms (roughly a one-Karat diamond) were placed on an anallytical balance, the balance would read.
Calculate the freezing point of a 0.2 m CaCl2 aqueous solution, assuming it dissociates completely to form ions in solution
A student determines the molar mass of methanol. She found that the equilibrium temperature of a mixture of ice and pure water was 0.4 degrees C on her thermometer
How would you demonstrate that phosphoglycerate mutase uses an enzyme bound phosphate
A given mass of radium is over a million times more radioactive than the same mass of uranium
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