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Consider a hypothetical equilibrium that exists between compounds A and B at room temp (298 K). The ?G‡ for the forward reaction (conversion of A to B) is 22 KJ/mol. Likewise ?G‡ for the reverse process is 34 KJ/mol. A. Calculate ?G0 for the forward reaction and construct a potential energy diagram for the conversion of A to B. Be sure to place the transition state in accordance with the Hammond Postulate. B. a flask containing a mixture of A and B at equilibrium was discovered, and the concentration of A at room temperature was determined experimentally to be 3.1 x 10^-2 mol/L. What is the concentration of B?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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