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Synthesis of aromatics1. On the basis of electronic theory, explain the following observations:
a. The -N(CH3)2 group is an ortho, para director, and strongly activates the ring, whereas the -N(CH3)3 group is a meta director and deactivates the ring toward electrophilic substitution.b. The -NO2 group is a meta director, and its presence on the ring makes electrophilic substitution more difficult as compared with the -NH2 group, which is an ortho, para director.
2. Devise a suitable reaction sequence in which each of the following compounds can be prepared from benzene in good yield. Assume ortho and para isomers are separate from one another, and use any other reagents you desire.a. p-Bromoisopropylbenzeneb. m-Nitrobenzenesulfonic acidc. p-Tert-butylbenzenesulfonic acidd. m-Xylene
A voltaic cell is based on the reaction Sn + I2 = Sn2+ + 2I-.
2.4 g of a hydrocarbon fuel is burned in a calorimeter that contains 262 grams of water initially at 25.00 C. After the combustion, the temperature is 26.55 C.
C2H6+O2 ---> CO2+H2O Calculate the mass of H2O that should form if 1.5 g of C2H6 is combusted in the presence of 2.5 g of O2.
The average concentration of calcium ion in seawater is 412 mg of calcium ion per kg of seawater. What is the molarity of the calcium ion if the density of the seawater is 1.025 g/mL?
In the following reaction, how many grams of NaBr will produce 244 grams of NaNO3? Pb(NO3)2(aq) + 2 NaBr(aq) PbBr2(s) + 2 NaNO3(aq)
Write the structure of the conjugate acid of this base while consider the base monosodium phosphate, Na (HO)2P( O)O also explain why an aqueous solution of monosodium phosphate would be ineffective for extracting benzoic acid? pKa of this conjugat..
Describe how branched-chain fatty acids affect the fluidity of membranes and rank the following fatty acids in the order of increasing solubility in water.
When 83.6 joules of heat is added to 2 grams of water at 10 degrees Celsius, the temperature of the water increases to what value?
the temperature of a 4.00L sample of gas is changed from 10.0c to 20.0c. what will the volume of this gas be at the new temperature if the pressure is held constant?
Ozonolysis from unknown compound, A compound, A, c6h8, yields a single organic product, B, upon ozonolysis and absorbs two moles of hydrogen on catalytic hydrogenation to give C.
If the methane contained in 3.00 L of a saturated solution at 25 was extracted and placed under STP conditions, what volume would it occupy.
A 34.32-g sample of a solid is placed in a flask. Liquid toluene, in which the solid is insoluble, is added to the flask so that the total volume of solid and liquid together is 96.44 ml.
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