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The maximum contaminant level (MCL) for barium (Ba) in drinking water is 2.0 mg/L. Barium can combine with sulfate (SO42-) to form BaSO4(s), which precipitates out of the water. This can be achieved by adding Na2SO4. You are to use your knowledge of equilibrium chemistry and solubility to answer the following: (a) What level of SO42- is required to reduce Ba2+ to the MCL? Assume there are no complexes with Ba2+ or SO42-. (b) For a flow of 1 MGD and an initial Ba2+ concentration of 10 mg/L, how much Na2SO4 must be added (lb/day) to accomplish removal of Ba2+ to the MCL? (c) Briefly discuss what the limitations might be in using precipitation of BaSO4(s) to remove Ba2+ from potential drinking waters. The following might be useful: BaSO4(s) = Ba2+ + SO42- pKsp = 10
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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