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Using the thermodynamic cycle in the tight binding KNI-764/HIV-1 protease example discussed in class, derive the Kapp= KKNI-764/(1+KAc-pepstatin[AcPepstatin]) for the apparent affinity constant (Kapp) for the competition assay between the weak (Ac peptstatin) and tight (KNI-764) inhibitor binding to HIV-1 protease. write expressions for HIV-1 protease complexed with each of the inhibitors individually, and remember that in the competition assay, only the unbound protein can bind KNI-764
2-Methylpentane and 4-methyl-2-pentanone are constitutional isomers with the molecular formula C6H12O.each shows a molecular ion peak in its mass spectrum at m/z 100.
To study the effect of a weakly acidic medium on the rate of corrosion of a metal, a chemist prepared a buffer solution by making it 0.11 M NaC2H3O2
The isomerization of cyclopropane follows first order kinetics. The rate constant at 700 K is 6.20*10^-4 min-1, and the half life at 760 K is 29 min. Calculate the activation energy for this reaction.
The rate constant of a reaction increases by a factor of 2 when the temperature is increased by 10C above room temperature (25C). Calculate the activation energy for this reaction.
A round plate having a diameter of 30.0 cm is being silver plated on one side, by electrolysis of silver nitrate, where the plate is the cathode
method would be a quick way to detect the presence of bromine/chlorine?
What was the percentage by mass of Mg(OH)2 in the original sample? When Mg(OH)2 or Al(OH)3 reacts with HCl(aq), the products are a chloride and water.
how many mL of 1.00 M hydrochloric acid is needed to prepare a 100.0 mL solution of hydrochloric acid with pH = 5.0 that also contains 0.01667 M MgCl2?
If a temperature of a gas at 1.00atm and 8.00C is increased, resulting in a change of pressure, which equation would you use to calculate the new pressure.
Consider the following reversible reaction. In a 1-liter container the following amounts are found in euilibrium at 400 deg C., 0.0536 mole N2, 0.599 mole H2, and 0.0437 mole NH3. Evaluate Kc = N2(g) + 3 H2(g)-> 2 NH3(g) answer in significant figu..
What will be the total vapor pressure (in torr) of a solution prepared by mixing equal masses of the two liquids?
What role do the potassium chloride (KCl) and potassium sulfate (K2SO4) play in this experiment
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