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A saturated solution of calcium iodate, Ca(IO3)2, is created by suspending a small amount of pure solid of Ca(IO3)2 in 50.0 mL of distilled water. After allowing equilibrium to be established, a 10.0-mL sample of the saturated solution is pipeted into an Erlenmeyer flask, and about 20 mL of de-ionized water is added to this sample, followed by about 1 cm3 of solid KI and 1 mL of 2.0 M HCl. The addition of excess KI and HCl converts all of the IO3- present in the sample to molecular iodine according to the following equation. IO3-(aq) + 5 I-(aq) + 6H+(aq) ? 3 I2(aq) + 3H2O(l) (Eqn-1) The iodine produced by the above reaction is then titrated with 0.0250 M Na2S2O3 using starch indicator, which requires 29.0 mL of 0.0250 M Na2S2O3 to reach end-point. The stoichiometric reaction between iodine and thiosulfate is represented by the following net ionic equation. I2(aq) + 2 S2O32-(aq) ? 2 I-(aq) + S4O62-(aq) (Eqn-2) Using Eqn-1 and Eqn-2, write a balanced net ionic equation that shows the stoichiometric relationship between iodate, IO3- and the thiosulfate, S2O32-, in acidic solution. (b) Use the equation derived from (a) and the data gi
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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