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It is often useful to be able to anticipate, without doing a detailed calulation, whether an increase in temperature will result in a raising or a lowering of a reaction enthalpy. The constant-pressure molar heat capacity of a gas of linear molecules is approximately 7/2R, whereas that of a gas of non-linear molecules is approximately 4R. Decide whether the standard enthalpies of the following reactions will increase or decrease with increasing temperature
(a) 2H2(g)+O2(g)---> 2H2O(g)(b) N2(g)+3H2(g)----> 2NH3(g)(c)CH4(g)+2O2(g)---->CO2(g)+2H2O(g)
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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