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A formate buffer (pka = 3.75) is prepared by mixing 50 mL of a 4 M formic acid and 2 g of solid sodium hydroxide (MW= 40g/mol) in total volume of 1.0 L. A peptide with the amino acid sequence C-P=T-Y-R-L-D-Q (MW = 995.12 g/mol) is dissolved in this solution at a concentration of 5 micromol.
a. What is the pH of this solution?
b. What is the net charge of the peptide in solution?
c. Calculate the approximate pH at which this peptide would have a net charge of zero.
you dissolve 15.0g of sucrose C12H22O11 in a cup of water (225g) what is the freezing point of solution (kf of water is -1.86).
A 0.1mL Pure Acid phosphatase (0.5mg/ml) hydrolyzes 0.2mmol of pnPP wall in 5 min. what is the specific activity?
If 5.0 g of Al reacts with 4.45 g of O2, what is the empirical formula of aluminum oxide? (Type your answer using the format CO2 for CO2.)
A half-life of phosphorus-32 =14.0 days. starting with six grams of 32P, determine how many grams would remain after 112 days
A moth-ball, composed of naphthalene (C10H8), has a mass of 1.32 g. How many naphthalene molecules does it contain?
Use a systematic treatment of equilibrium to calculate the pH of a solution prepared by diluting 0.467 g of aniline (aminobenzene, C6H5NH2) to 100.0 mL.
What is the total pressure exerted by a mixture of 1.50 g H2 and 5.00 g N2 in a 5.00 L vessel at 25 ºC
what mass of sucrose should be combined with 501 g of water to make a solution with an osmotic pressure of 8.85 atm at 305 K? (assume density of solution is equal to the density of the solvent).
calculate the stoichiometric air-fuel ratio of a fuel blend containing 80 vol.% ethanol and 20 vol.% gasoline
The compound malonate is an analog of succinate and is a strong inhibitor of succinate dehydrogenase. The active site of the enzyme will bind to either molecule, however malonate will not undergo any reaction and gets stuck on the enzyme.
Explain the large disparity in the numerical results pf Part (a). Discuss the advantages and disadvantages of the three energy sources.
A 1.00-L gas sample at 100.°C and 589 torr contains 50.0% helium and 50.0% xenon by mass. What are the partial pressures of the individual gases?
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