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1. Why is the tetrabutylammonium cation relatively soluble in solvents of low polarity?
2. A list of atomic masses of the elements says that the mass of Br is 80 amu. In the mass spectrum of bromobenzene, no significant signal is seen at m/z 157. Two signals of nearly equal abundance are found at m/z 156 and m/z 158. Explain why this is so and show formulas of the two ions as 156 and 158.
A reaction at 25C is known to standard changes in free energy, enthalpy and entropy of -38.4 kJ/mol.96.3kJ/mol
Calculate the APF for (a) the simple cubic and (b) body centered cubic lattices as volume of atoms/volume of cell. (c) Which structure is more dense given atoms of equal mass? The edge length for simple cubic is 2r. Remember that each corner atom ..
What is the molarity of the acid of a mixture of 20.00 ml HCl (aq) + 14.25 ml of 0.2030 M NaOH
If a sample contains 79.0% of the R enantiomer and 21.0% of the S enantiomer, what is the enantiomeric excess mixture
The oxygen atom with its 2s orbital forms a s bond with one of the three sp2 hybrid orbitals of the carbon atom; the two hydrogen atoms with their 1s orbitals each form a s bond with one of the three sp2 hybrid orbitals of the carbon atom.
During an experiement, 225 mL of Wet H2 was collected over water at 29 Celcius, with a total pressure of 748 torr. How many grams of Zinc were consumed as a result
Zn(s) + 2 HCl(aq) → H2(g) + ZnCl2(aq) If 1.26 L of H2 gas are formed at STP, how many g of HCl reacted?
you have 100 ml graduated cylinder containing 50 ml of water. you drop a 154 g piece of brass d 8.56 gcm3 into the
Calculate the wavelength of each of the following frequencies of electromagnetic radiation. 1105 kHz (typical frequency for AM radio broadcasting) (assume four significant figures)
You are given 100g agarose (which makes a gel when dissovled in boiling water) and 100 ml buffer. Show how you would prepare 50 ml of a 1.2% agarose gel. weight and volume do not add up
Calculate the pH of each of the following solutions. (a) 0.100 M propanoic acid (HC3H5O2, Ka = 1.3 x 10^-5) (b) 0.100 M sodium propanoate (NaC3H5O2) (c) pure H2O (d) 0.100 M HC3H5O2 and 0.100 M NaC3H5O2
metal a was determined to be 95extracted into methylene chloride with dethizone at ph6 when equal volumes of aqueous
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