Evaluate the ratio of equatorial to axial tert-butylcyclohe

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Reference no: EM13555501

Gibbs free energy differences between axial-substituted and equatorial-substituted chair conformations of cyclohexane were given in table 2.4

a) Calculate the ratio of equatorial to axial tert-butylcyclohexane at 25 degrees C

b) Explain why the conformation equilibria for methyl, ethyl and isopropyl substituent are comparable but the conformational equilibrium for tert-butylcyclohexan lies considerably farther toward the equatorial conformation

Reference no: EM13555501

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