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In this problem you will estimate how much gas is lost from a 2 gallon high density polyethylene (HDPE) can in a year. Assume the walls of the container are 2 mm thick and for simplicity the container is cubic in form. Assume gasoline has a density of 0.7 g/cm3. The Polymer Handbook (Wiley, 3rd Ed., 1989) lists the diffusion coefficient for hexane (assume that is gasoline) as approximately 1x10-8 cm2/s at ambient temperature. When a 1 gram piece of the HDPE (density = 1 g/cm3) is immersed in gasoline for a long time it increases its weight to 1.001 grams. This provides an estimate of the equilibrium concentration of gasoline in contact with the plastic. What percent of the gasoline in the initially full 2 gallon container is lost in a year?
When the elements below are burned, they emit light of a specific wavelength, listed below. Calculate the frequency for each and determine whether the light emitted is visible, UV, infrared, etc.
An alkyne of six carbon atoms gives the same single product in its reaction either with BH3 in THF followed by H2O2 /OH-, or with H2O/Hg2 /H3O . Draw the structure of the alkyne (containing only carbon and hydrogen atoms).
Treatment of A with zinc amalgam and HCl affords an optically active, dextrorotatory hydrocarbon C. Identify compounds A, B, and C, including stereochemical configurations. Be sure to explicitly draw H and both wedge/dash bonds at any configuratio..
Calculate the Standard Enthalpies & Standard Entropies for each reactant & product at the temperature given first, then determine the ?H°rxn and ?S°rxn at 1600 K Zr(beta) + O2 = ZrO2(beta) Other information:
Why would it be more appropriate to put the elements La and Ac in the bottom two periods and put Lu and Lr in the transition metals? Why don't we see the use of any sublevels higher than the f sublevel?
Calculate the number of theoretical plates N in the column of length L in 20 cycles. The observed resolution is 1.81. B) Now, calculate the plate height in the column in m.
At 123?C, the pressure of a sample of nitrogen is 1.45 atm. What will the pressure be at 267?C, assuming constant volume?
a 130g piece of metal is heated to 286C and dropped into 87.0g of water at 26C, if the final temperature of the water is 58.3C.
Determine the partial pressure and total pressure of the gases and Find the partial pressure of carbon dioxide in a gas mixture
A piston has an external pressure of 14.0 torr. How much work has been done if the cylinder goes from a volume of 0.130 liters to 0.530 liters.
Provide the reagents necessary for the following syntheses. More than one step may be required. (a) (b) (c) (d) (e) (f)
Multiple choice questions in Nuclear chemistry - As the temperature of a sample of a radioactive element decreases, the half-life will
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