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1. Ideal gas
Consider N O2 molecules in a container of volume V at a pressure of P=1 atm and atemperature of T=298K.
a. Calculate the collision frequency Z1 of a single O2 molecule under these conditions. Assume the diameter of an O2 molecule is d= 2.92x10^-10 m. Assume oxygen behaves ideally under these conditions.
b. Calculate the mean free path l and the diffusion constant D of a molecule in part a.
c. The resistance of a fluid to macroscopic flow is called the shear viscosity. The more viscous a fluid, the greater the force that is required to cause it to move through a narrow tube. For an ideal gas the viscosity ? is related to the number of molecules N the average speed c , the mass m of a molecule and the mean free path l by ? ˜ Ncml/2V. Calculate the viscosity of the gas in part a. Assume 1 mole of O2 molecules is in the container and the total volume is 1 cubic meter. What are the units of viscosity in terms of kilograms, meters, and seconds?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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