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Question - Pyruvate carboxylase catalyzes the carboxylation of pyruvate to give oxaloacetate. This pyruvate carboxylase reaction requires the coenzyme biotin, which is the prosthetic group of the enzyme. Draw a detailed and reasonable electron-pushing mechanism for the pyruvate carboxylase reaction that accounts for the formation of all products. Invoke generic acids and bases (A-H and B:, respectively), as necessary. Also draw the fused ring structure of biotin as part of your answer.
The concept of free energy allows prediction of spontaneity of a process by considering the changes in ________ and ________ during the process.
Silicon is widely used in the semi-conductor industry. Its isotopes and their anatomic masses are:Si-28 (27.9769amu), Si-29 (28.9765amu), and Si-30 (29.9794amu) Which is the most abundant
c2h6g o2g co2g h2oga consider the unbalanced equation above. how many grams of o2 are required to react with 13.0 g
why does ch3-ch2-o-h have a higher boiling point than ch3-o-ch3 even though they have the same molar
The equilibrium constant, Kp, is 7.8 x 1014 (Hint, this is a very large number, what does that imply?) Calculate the molar concentration of HF at equilibrium.
The vapore pressure of water at 16 degree celsius is 13.6 torr and it is 15.5 torr at 18 degree celsius. what is the vapore pressure at 17 degree celsius
Problem- The gas phase reaction A + B ? C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. Which one of the following would affect the value of the specific rate constant, k
How do the requirements that t and v are constant enter the derivation for delta Asys
A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Calculate Ecell when [Pb2+] = 0.616 M and [Mn2+] = 1.069 M. You should use the reduction potentials for Mn2+ is -1.18 V and for Pb2+ is -0.125 V.
calculate the concentration of Hg2 +2 in a saturated aqueous solution of (Hg2)3[Co(CN)6]2 which dissociates into mercurous ion and Co(CN)6 -3 (cobalticyanide).
the mass of a cube of iron is 434 g. iron has a density of 7.87 gcm3. what is the mass of a cube of lead that has the
Compute change of heat for the reaction of one mole of lead(ll) sulfide with oxygen and carbon, forming lead, sulfur dioxide, and carbon monoxide
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