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A) for the electrophilic addition of HCL to 2-methyl-2-pentene use curved arrow notation to show the formation of the markovniknov & anti-markovnikov product. Label the types of carbocation formed as intermediates in each reaction pathway & show the structures of both the transition states for each reaction pathway (must show bonds being broken and/or made in transition state structure, must resemble species closest in energy per Hammond postulate)
B) Draw one energy diagram showing both reaction pathways & label all transition states, intermediates and products as well as activation energies. you may assume that the overall reactions are both exergonic while the first step in each reaction is endergonic.
C) Which product (markovniknov or anti-markovnikov) will be major product? why?
Assuming that a neutron star has the same density as a neutron, calculate the mass in kilograms of a small piece of a neutron star the size of a spherical pebble with a radius of 0.10 mm.
If 3.30ml of vinegar needs 45.0ml of 0.130M NaOH to reach the equivalence point in a titration, how many grams of acetic acid are in a 1.10qt sample of this vinegar?
What volume of 0.1000 M NaOH is required to titrate a 0.1000 M propionic acid solution, CH3CH2COOH, Ka = 1.3 x 10-5 , to the equivalence point?
calculate E when 830.0 g of CH3OH(g) completely reacts at a constant temperature of 300 K and constant pressure of 0.95 atm.
The freezing point of t-butanol is 25.50C and Kf is 9.1C kg/mol. Usually t-butanol absorbs water on exposure to air. If the freezing point of a 10.0g sample of t-butanol is 24.59C. How many grams of water are present in the sample?
Calculate the standard reaction enthalpy for the oxidation of nitric oxide to nitrogen dioxide 2 NO(g) + O2(g) → 2 NO2(g)
How many milliliters of 0.200 M NaOH will be required to titrate 7 mL of 0.479 M H2SO4
Solubility of calcite (CaCO3) will increase with a decrease in temperature and decrease with an increase in temperature. This is because the solubility of calcite is dependent on the solubility of CO2.
At equilibrium the vessel is found to contain 0.566 g of H2. Calculate the equilibrium concentrations of H2, Br2, and HBr and Calculate Kc.
Important information about Thermochemistry, Glauber's salt, sodium sulfate decahydrate (Na2SO4 * 10H2O) undergoes a phase transition (that is melting or freezing) at a convenient temp of 32 degrees C
Determine the functional form of Phi(t) and the frequency of a pendulum bob whose mass is m and is attached to a massess rod of length l. Assume that the bob oscillates in the limit of small oscillations.
Write lewis structures for each of the following species. Use expanded octects as necessary.
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