Determining order of basicity of amines

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Help determining order of basicity of amines: (possibly could be explained using substitution, resonance, and hybridization effects)?

a) Why is Ph-NH2 LESS basic than NH3? 

b) Why is p-nitroaniline LESS basic than aniline? 

c) Why is pyridine MORE basic than aniline? 

d) Why is 3-nitropyrrole LESS basic than pyrrole which is LESS basic than imidazole?

Reference no: EM131910937

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