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Hydrogen peroxide (H2O2) behaves like an acid in water. It has a Ka value equal to 1.778x 10-12. When sold in stores, solutions of H2O2 are often 3.00% H2O2 by mass. The solution also contains a small amount of phosphoric acid (0.001% by mass) which stabilizes the solution as hydrogen peroxide easily decomposes. Since both hydrogen peroxide and phosphoric acid behave like acids in water, both acids will contribute H+ ions to the solution. The Ka for phosphoric acid is equal to 7.2 x 10-3. (HINT: assume the density of the solution is 1.000 g/ml). The two reactions that you will need are given below: (8 pts) a.) Determine the concentration (M) of H2O2 and H3PO4 from their provided mass percents. Assume 1.00 L of solution (Hint, review how a mass % is determined - it will help you identify the units and their respective locations before you convert). H2O2 (aq) + H2O (l) ? H3O+1 (aq) + HO2-1 (aq) H3PO4 (aq) + H2O (l) ? H3O+1(aq) + H2PO4-1 (aq) b.) Mathematically determine which acid contributes a larger concentration of H3O+ ions into the solution, be sure to report the H3O+ concentrations for both, label them clearly, and identify which substance creates a larger concentration?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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