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Problem 12.3: The table below gives the excess enthalpy for the system acetone(1)-water(2) at 25 °C, 1 bar. a) Calculate the partial molar enthalpy of each component at x1 = 0.5, 25 °C, 1 bar. The reference state for each component is the pure liquid at 25 °C, 1 bar. b) Repeat the previous part with the reference state for water changed to the pure liquid at 2 bar, c) A solution that contains 50% by mole acetone is mixed with an equal volume of a solution that contains 80% by mole acetone. The mixing takes place in a heat bath at 25 °C. Determine whether any amount of heat is exchanged between the system and the surroundings. If so, calculate that heat and report whether the mixing is endo- or exothermic.
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