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The presence of iron ions in drinking water can cause discoloration of the water, a change in taste, darkening of prepared foods, and, in some cases health problems. A slow and uniform precipitation of iron, as Fe(OH)3 can be used as a gravimetric analysis technique. This can be facilitated when the precipitating OH- is generated within the solution using urea decomposition: H2NCONH + H2O CO2 + 2 NH3 The NH3 generated converts to OH- via this reaction: H2O + NH3 NH4+ + OH-
(A) A solution containing 1.80 x 10-3 M Fe3+ is treated with urea to precipitate the Fe3+ as Fe(OH)3. What molarity of urea is needed to precipitate the iron if a 30% excess of urea is desired? ______ M urea
(B) The Fe(OH)3 produced by the process described above is gelatinous so is ignited to convert it to Fe2O3. What is the percent of iron in a solution if 100.0 grams of the solution yielded, upon proper treatment, 0.715 grams of Fe2O3? Note first determine the gravimetric factor for this precipitation.
Gravimetric factor = _______
Mass percent Fe = _______%
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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