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100. kg of atmospheric air (whose composition is given in Example) is cooled in a 0.500 m3constant volume container to 200. K. Determine the mixture pressure using Dalton's compressibility factor.
Compare this result with that obtained by assuming ideal gas (i.e., Zm = 1.00) behavior.
Example :
The molar composition of air that is normally used to determine the thermodynamic properties of air at standard temperature and pressure is
Component
Molar %
Nitrogen
78.09
Oxygen
20.95
Argon
0.930
CO2 and trace gases
0.0300
Total
100.00%
Determine (a) the equivalent molecular mass, (b) the gas constant for this mixture, and (c) the composition of air on a mass (or weight) basis.
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