Determine the equilibrium constant for the reaction

Assignment Help Chemistry
Reference no: EM13701807

A reaction mixture of 4.00 mL of 0.00200 M SCN and 5.00 mL of 0.00200 M Fe^3+ is diluted to 10.00 mL with 0.1 M HNO3 to form the blood-red FeNCS^2+ complex. The equilibrium molar concentration of the FeNCS^2+ determined from a calibration curve, is 1.5 x 10^-4 mol/L. Calculate, in sequence each of the following quantities in the aqueous solution to determine the equilibrium constant for the reaction.


Fe^3+(aq) + SCN-(aq)<-------->FeNCS2+(aq)

a. moles of FeNCS^2+ that form in reacting equilibrium
b. moles of Fe3+ that react to form the FeNCS^2+ at equilibrium
c. moles of SCN- that react to form the FeNCS^2+ at equilibrium
d. moles of Fe^3+ initially placed in the reaction system
e. moles of SCN- initially placed in the reaction system
f. moles of Fe^3+ (unreacted) at equilibrium
EQUATION:
mol Fe^3+ equilibrium = mol Fe^3+ initial - mol Fe^3+ reacted
g. moles of SCN- (unreacted) at equilibrium
EQUATION:
mol SCN- equilibrium = mol SCN- initial - mol SCN- reacted
h. molar concentration of Fe^3+ (unreacted) at equilibrium
i. molar concentration of SCN- (unreacted) at equilibrium
j. molar concentration of FeNCS^2+ at equilibrium
k. Kc= ([FeNCS^2+]) / ([Fe^3+][SCN-])

Reference no: EM13701807

Questions Cloud

Locate vendors of biometric products : Using the Web, locate vendors of biometric products. Find one vendor with a product designed to examine each characteristic mentioned in your textbook. What is the CER associated with each product? Which would be more acceptable to users? Which..
Twice the bicarbonate concentration : In water open to the atmosphere (CO2 = 390 ppmv), at what pH must the water be buffered so that the carbonate concentration is twice the bicarbonate concentration?
Pure water is at equilibrium with excess caco3 : Pure water is at equilibrium with excess CaCO3 (s) and MgCO3 (s). If the water has a pH of 8.61 and is open to the atmosphere (CO2 = 390 ppmv), calculate [Ca2+] and [Mg2+]. (for MgCO3 (s), pKs = 7.45)
Ocean water typically contains approximately 35 moles : Ocean water typically contains approximately 35 moles of salt ions dissolved in each 1000 moles of water. Assuming that ocean water has the same density as pure water, use this ratio to determine the molarity of the solution and then calculate ..
Determine the equilibrium constant for the reaction : A reaction mixture of 4.00 mL of 0.00200 M SCN and 5.00 mL of 0.00200 M Fe^3+ is diluted to 10.00 mL with 0.1 M HNO3 to form the blood-red FeNCS^2+ complex. The equilibrium molar concentration of the FeNCS^2+ determined from a calibration curve..
Politically speaking, it is insufficient to say : Politically speaking, it is insufficient to say that power and violence are not the same. Power and violence are opposites; where the one rules absolutely, the other is absent
Describe the new types of marketing communications : In a 500 to 1000 word narrative, describe the new types of marketing communications available on the web, describe their advantages or disadvantages, and outline their changing effectiveness and cost.  Have firms communicated with you online as..
Spam is still in existence because spam still works : Spam is still in existence because spam still works. Take a stance on email marketing, for or against. Using the information from your text and from your experience, explain why email marketing works, or why it doesn't work. Keep in mind that ..
Non-alcholic beverage : Provide the following information to set the foundation for your non-alcholic beverage (NAB) business plan.1.Create your NAB company name and explain its significance.2.Develop your company's Mission Statement and provide a rationale for its componen..

Reviews

Write a Review

Chemistry Questions & Answers

  Define the concentration of tce in the aqueous phase

TCE is added to the aqueous phase so that initally it has an aqueous phase concentration of 100 ppb. After the system equilibrates, what will be the concentration of TCE in the aqueous phase

  Explain what was the temperature of the cu

If 40.0 g of Cu is placed into 100.0 g of H20 at a temperature of 20.0*C and if the temperature of the water rises to 23.0*C, what was the temperature of the Cu

  Define the structure of camphor

Draw the structure of camphor and show which C-C bond must be broken to form the unwanted by-product

  Explain when aluminum is produced by electrolysis

When aluminum is produced by electrolysis we get 5.68 tons of aluminum and 5.04 tons of oxygen. What is the empirical formula of the compound that is being electrolyzed

  The solvent molecules immediately cluster around the ions

When an ionic solid is added into a solvent, you can see that the ionic solid dissociates into its respective cations and anions. The solvent molecules immediately cluster around the ions.

  Explain arsenic acid is a triprotic acid

Arsenic acid (H3AsO4) is a triprotic acid with Ka1 = 5. 10-3, Ka2 = 8. 10-8, and Ka3 = 6. 10-10. Calculate [H + ], [OH ? ], [H3AsO4], [H2AsO4? ], [HAsO42- ], and [AsO43- ] in a 0.62 M arsenic acid solution.

  Explain a polypeptide containing only glutamic acid residues

Polyglutamic acid, a polypeptide containing only glutamic acid residues, spontaneously coils into an a-helix at pH 1 but not at pH 7.

  Explain what halide was present in the unknown

Problem- In the experiment of establishing the relative reactivity of Halogens and Halide Ions a student performed the following two tests on an unknown solution containing one halide ion.

  Calculate the change in entropy

calculate the change in entropy that occurs when 18.53 g of ice at -10.7°C is placed in 54.05 g of water at 100.0°C in a perfectly insulated vessel.

  Explain what is the molecular formula combustion analysis

When a 0.369 g sample was studied by combustion analysis, 0.662 g of CO2 and 0.0897 g of H2O formed. How many moles of each of the following were in the original sample? C: ? H: ? Cl: ? What is the molecular formula?

  Evaluate the wavelength and frequency of an emitted gamma

The radioactive Co-60 isotope is used in nuclear medicine to treat certain types of cancer. Calculate the wavelength and frequency of an emitted gamma particle having the energy of 1.29 x 10^11 J.

  What is the partial pressure of helium gas

A gas mixture with a total pressure of 765 contains each of the following gases at the indicated partial pressures: , 118 ; , 229 ; and , 187 . The mixture also contains helium gas. What is the partial pressure of helium gas.

Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd