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For the lanthanoids, the 4f orbitals are small and do not participate in bonding. Assume however that the 4f orbitals are big enough to participate in bonding alongside with the 6s orbitals.
Draw the expected trend in the melting temperatures for the lanthanides starting with La and ending with Yb. Support your conclusions by showing the DOS and bonding character plots for the element with the highest melting temperature.
Note: assume that the d orbitals do not participate in bonding and a d-electron is donated to the 4f shell. Neglect the lanthanoid contraction. The trend obtained will be different from the real melting temperatures.
The standard enthalpy of formation of gaseous H2O at 298 K is -241.82 kJ mol-1. Estimate its value at 75 °C given the following values of the molar heat capacities at constant pressure:
Explain why it is a good technique to slow the addition of NaOH titrant near the stoichiometric point.
The composition of a gas on a dry basis is 71.0 mole% N2, 12.0% O2, 12.0% CO2, and 5.0% CO. If the mole fraction of water is 0.160, what is the gas composition on a wet basis?
a system at equilibrium or striving to reach equilibrium responds in a way that best ac- commodates or reduces any
Describe how you would make 500 mL of 0.150 M Na2SO4 given 1 kg of Na2SO4, a distilled water supply, a balance, anf a 500-mL volumetric flask.
Based on the stereochemistry of the addition of bromine to cinnamic acid, write structure of the dibromide product(s) that you think will be formed as the result of the reaction of Z-2-pentene with bromine
oxymercuration of an alkene to a ß-hydroxyl-alkyl mercury specie B. addition to bromine to an alkene C. hydroboration of an alkene D. E2 dehydrohalogenation E. opening an epoxide with a nucleophile
How many moles of methanol are present in a 150.0 gram sample of methanol,CH3OH
Chromium is produced by reacting its oxide with aluminum. If 76 grams of Cr2O3 and 27 grams of Al completely react to form 51 grams of Al2O3 how many grams of Cr are formed
If the reaction 2 NO(g) + O2(g) ? 2 NO2(g) is carried out at STP, what is the total pressure? What is the temperature at STP
1.70 atm of I2 and 1.30 atm of Br2 are loaded into an evacuated container. The following reaction takes place with Kp = 117.6 Calculate the equilibrium partial pressure of bromine gas. No approximations can be made because the equilibrium constant..
Electrochemistry has a wide range of applications. Research and describe one job, outside the field of chemistry, that uses electrochemical knowledge
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