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(a) Draw the ?-only molecular orbital diagram for ML6 using AOM. Now, show what happens to the orbitals of the MO diagram after the Jahn-Teller tetragonal distortion is added for a d4 high spin complex. (Hint: The Jahn-Teller effect removes degeneracies in the MO diagram. Which MOs are affected?)
(b) Next consider a ?-donor ligand complex such as MX6n+ (x=halide) and its AOM diagram. Again the MO's are affected by a tetragonal distortion, changing both the molecular orbitals identified in the ?-only diagram as well as the molecular orbitals with ? symmetry. Sketch an example of one of these ? interactions which demonstrates why ? symmetry orbitals are also affected by the distortion.
Balance the following redox reactions. Break your answer down into individual steps not just the final balanced numbers. a) P4(s) + NO3^- ==>> H2PO4^- +NO(g) (acidic solution)
A hot-air dryer is used to reduce the moisture content of 1500kg/min of wet wood pulp from 0.75 kg H2O/kg dry pulp to 0.15wt% H2O. Air is drawn from the atomosphere at 28C, 760mm Hg, and 50% relative humidity, sent through a blower-heater, and the..
25.00 ml aliquots of thiis solution was titrated with monoprotic strong base NaOH (0.0800 M). The titre volume of NaOH was 40.00ml. Calculate the molecular weight of H2A.
What volume (V) of 2.20 M NaOH solution must you add in order to prepare an acetate buffer of pH = 4.26? (The pKa of acetic acid is 4.76.)
how many grams of ammonium nirtate must have reacted if 3.75dm3 of nitrogen gas was collected over water at 26C and 97.8 kPa
An analyst is to determine the molarity of a NaOH solution. Three aliquots of standard KHP are weighed out 0.3078g, 0.4967g, and 0.3821g
Compute the enthalpy change for this reaction per mole of this substance and dissolves via the reaction and the temperature of the solution rises to twenty eight degree celsius.
What is the final concentration of a solution made from 7.1 mL of 0.8 M CuSO4 and 14.3 mL of water?
What percent (by moles) of He is present in a helium-oxygen mixture having a density of 0.518g/L at 25 ?C and 721
Write the equations describing the electrode reactions and the net cell reaction for this electrochemical cell containing indium and cadmium:
Consider the titration of 82.0 mL of 0.147 M Ba(OH)2 by 0.588 M HCl. Calculate the pH of the resulting solution after the following volumes of HCl have been added.
A sample of an unknown peptide undergoes a single round of Edman degradation, which liberates ATZ-Gly. Another sample of the peptide is treated with trypsin, and a third sample is treated with chymotrypsin. The table below shows the fragments.
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