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a) When HCl is added to 1,3-butadiene either 3-chloro-1-butene or 1-chloro-2-butene forms. Which product is more stable? Explain.
b) Explain why at low temperatures, e.g. -80oC, when HCl is added to 1,3-butadiene the major product is 3-chloro-1-butene.
c) Explain why at +80oC when HCl is added to 1,3-butadiene the major product is 1-chloro-2-butene.
d) 3-chloro-1-butene is converted to 1-chloro-2-butene at +80oC, i.e. give the mechanism for the conversion. (Note: AlCl3 can be used to catalyze the conversion.)
A solid block of exactky 100.0 cm 3 has a mass of 153.6g. Determine its density. Will the block sink or float on water?
At 2000°C the equilibrium constant for the reaction is Kc = 2.4 x 10^3. , 2 NO(g)-> N2(g) + O2(g) If the initial concentration of NO is 0.100 M, what are the equilibrium concentrations of NO, N2, and O2?
A tank contains helium gas at 490. mmHg, nitrogen gas at 0.750 atm, and neon at 520. torr. What is the total pressure in atm?
Calculate the amount of heat required to raise the temperature of 1500g of water from 25C to 63C
The compound As2I4 is synthesized by reaction of arsenic metal with arsenic triiodide. If a solid cubic block of arsenic (d 5.72 g/cm3) that is 3.03 cm on edge is allowed to react
Carbon disulfide, CS2, is a volatile, flammable liquid. It has a vapor pressure of 400.0 mmHg at 28.0°C and 760.0 mmHg at 46.5°C. What is the heat of vaporization of this substance?
what would be the effect on the pH of adding 1 gram of sodium oxalate to the original buffer
Create an outline of no more than 10 steps describing how you will regenerate the column, load your sample and collect the hydronium ion released.
How much energy (in kilojoules) is required to convert 110 mL of diethyl ether at its boiling point from liquid to vapor if its density is 0.7138 ?
Ammonia can be oxidized in oxygen as shown: 4 NH3(g) + 3 O2(g) 2 N2(g) + 6 H2O(g). When 0.791 mol of NH3 and 0.814 mol of O2 are placed in a 1.00 L container at a certain temperature,
An aqueous antifreeze solution is 35.0% ethylene glycol (C2H6O2) by mass.
Design a tube and shell heat exchanger for the fluids and duty given for you and complete Project Management tasks
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