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A. An unknown liquid boiling around 185 +/_ 5 degrees C in 5% HCl but is insoluble in water and in a pH 5.5 buffer. Shaking the unknown with p-touluenesulfonyl chloride in aqueous NaOH produces a clear solution that, when acidified, yields a white precipitate. Give its name and structure.
B. An unknown liquid boiling around 185 +/_ 5 degrees C in 5% HCl and in a pH 5.5 buffer but is insoluble in water. Shaking the unknown with p-touluenesulfonyl chloride in aqueous NaOH produces a white precipitate that doesn't dissolve in dilute HCl. Give its name and structure.
Determine the number of CH2CH2 monomeric units, n, in one molecule of polyethylene with a molar mass of 40,000 g.
When optically active B was treated with CrO3 in pyridine, an optically inactive sample of A was obtained. Heating A with hydrazine in base gave hydrocarbon C, which, when heated with alkaline KMnO4, gave carboxylic acid D. Identify compounds A, B..
A sample of oxygen gas at a pressure of 0.996 atm and a temperature of 195oC, occupies a volume of 714 mL. If the gas is cooled at constant pressure until its volume is 544 mL, the temperature of the gas sample will be oC.
When 5.00 g of fructose, C6H12O6, (FW 180.16 g/mol) is burned in a calorimeter whose heat capacity is 29.7 kJ/oK, the temperature increases by 2.635oK. Calculate the heat of combustion of fructose in kJ per mole.
a 10.9-g mixture of nitrogen and carbon dioxide is found to occupy a volume of 8.88 l when measured at 641.9 mmhg and
The final volume of the system is 58.0 L. What was the initial volume of the system if the internal energy of the system decreased by 102.5 J?
How many milliliters of 0.100 M NaOH(aq) would be needed to completely neutralize 50.0 milliliters of 0.300 M HCl(aq)
Liquid NCl3 in a 2.5 L closed container is heated until it decomposes completely to gaseous products. The resulting mixture exerts a pressure
If a 1000 kilogram sample of rock is 0.021% gold by mass. How much zinc is needed to react with the gold extracted from the rock?
from the ratio of the mass of the black product to the initial 5g placed in the flask could the remaining black
the threshold wavelength for potassium metal is 564 nm. what is its work? what is the kinetic energy of electrons ejected if radiation of wavelength 410 nm is used?
at a particular temperature k2.0x10-6 moll for the following reaction 2co2 g at equilibrium with 2cog o2 g if 2.1 mol
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