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You wish to measure the concentration of methyl benzoate in a plant stream by gas chromatography. You prepare a sample of butyl benzoate to use as an internal standard. A preliminary run, shown at the right involved a solution containing 1.69 mg/mL of methyl benzoate (peak A) and 1.86 mg/mL of butyl benzoate (peak B). The area of peak A was determined to be 354 and of peak B to be 419 (measured in arbitrary units by the computer). To measure the sample, 1.00 mL of a standard sample of butyl benzoate containing 2.59 mg/mL was mixed with 1.00 mL of the plant stream material, and analysis of the mixture gave a peak area of 463 for peak A and 425 for peak B. What is the concentration of the ethyl benzoate in the plant stream?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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