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The amino acid L-histidine has three acid-base equilibria, with pKa values of 1.78, 5.97, and 8.97.
(a) Plot the fraction of solute species present in solution in the pH range 0 to 14.
Use the graph to determine
(b) The major species present in solution at pH = 7.5.
(c) The pH value at which equal amounts of the singly and doubly deprotonated forms are present.
(d) The pH necessary to achieve greater than 99% fully deprotonated histidine.
(e) The pH range for which three different deprotonated forms are present in significant quantities.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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