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Part III. Redox and Thermodynamics 1. Sketch galvanic cells based on the following overall reactions. Show the direction of electron flow, the direction of ion movement through the salt bridge, and identify the cathode and anode. Give the overall balanced reaction. Assume that all concentrations are 1.0 M and that all partial pressures are 1.0 atm. IO3- (aq) + Fe2+ (aq) ? Fe3+ (aq) + I2 (aq) 2. Write the standard line notation for the cell in Part III Question #1. 3. Calculate the E°cell values for the galvanic cell in Question #1. IO3- (aq) + Fe2+ (aq) ? Fe3+ (aq) + I2 (aq) 4. Calculate ?G° at 25 °C for the reaction in Part III Question #1. 5. Assume that the reaction is at equilibrium at 25 °C (under standard conditions. Calculate the equilibrium constant K.
Calculate each of the following quantities for this change of state. If it is impossible to calculate a quantity from this given information, state this. (a) q; (b) w; (c) ?U; (d) ?H.
A strip of electrolytically pure copper weighing 3.178 gram is strongly heated in a stream of oxygen until it is all converted to a black oxide. The resultant black powder weighs 3.978 g. What is the formula of the oxide?
If NF can interact with a transition-metal ion to form a chemical bond, what type(s) of ligand-metal interactions would be most important. Would you expect NF to be high or low in the spectrochemical series. Why
Calculate the energy produced when 15 grams of liquid methanol (CH3OH) is completely burnt in air to produce carbon dioxide gas
What practical advantage does an extraction solvent that is denser than water have over one that is less dense
What is the difference between gradient elution and isocratic elution in High performance liquid chromatography
Consider the following standard reduction potentials in acid solution: Cr3+ + 3e- ? Cr Eo = -0.74 V, Co2 + 2e- ? Co Eo = -0.28 V, MnO4 + 8H+ + 5e- ? Mn2+ + 4H2 Eo = +1.51 V
Consider a mixture is a 2 dm^3 flask at 27 degree C. For each of the following mixtures, calculate the partial pressure of each gas, the total pressure, and the compositon of the mixture in mole percent. (Hint: for mole percent take your answer fo..
What is the molarity of a permanganate solution if it takes 10.0 mL of 0.200M iron(II) solution to completely react with 15.7 mL of the permanganate solution
A galvanic cell is constructed with a silver-silver chloride electrode, and a nickel strip immersed in a beaker containing 1.56 x 10-2 M solution of NiCl2. Determine the balanced cell reaction and calculate the potential of the cell. Enter in Volt..
What is the maximum mass of aluminum chloride that can be formed when reacting 18.0g of aluminum
What is the de Broglie wavelength in cm, of a 12.9 g hummingbird flying at 1.14 102 mph? (1 mile = 1.61 km.)
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