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1-butanol and chlorobenzene form a minimum boiling point azeotropic system. The mole fraction of 1-butanol in the liquid (x) and vapour (y) phases at 1.000 atm is given below for a variety of boiling temperatures
T/K 396.57 393.94 391.60 390.15 389.03 388.66 388.57
X 0.1065 0.17 0.2646 0.3687 0.5017 0.6091 0.7171
Y 0.2859 0.3691 0.4505 0.5138 0.5840 0.6409 0.7070
Pure chlorobenzene boils at 404.86 K. (a) Construct the chlorobenzene-rich portion of the phase diagram from the data. (b) Estimate the temperature at which a solution whose mole fraction of 1-butanol is 0.300 begins to boil. (c) State the compositions and relative proportions of the two phases present after a solution initially 0.300 1-butanol is heated to 393.94 K
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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