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A 0.150 M aqueous solution of the weak inorganic acid HA was prepared from the pure compound, and three 50.0 mL aliquots were transferred to 100.0 mL volumetric flasks. Solution 1 was diluted to 100.0 mL with 1.0 M HClO4; solution 2 with 1.0 M NaOH, solution 3 with water. A 25.0 mL aliquot of each was extracted with 25.0 mL of n-hexane. The extract from solution 2 contained no detectable trace of A-containing species, indicating that A^- is not soluble in the organic solvent. The extract from solution 1 contained no ClO4- or HClO4 but was found to be 0.0454 M in HA (by extraction with standard NaOH and back-titration with standard HCl). The extract from solution 3 was found to be 0.0225M in HA. Assume that HA does not associate or dissociate in the organic solvent, calculate a.) the distribution ratio for HA between the 2 solvents. b.) the concentration of the species HA and A^- in aqueous solution 3 after extraction c.) The dissociation constant of HA in water.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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