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4) You have to separate 4-toluic acid (a strong acid, pKa 4.36 - look up structure) from 4-bromoaniline (a base - look up structure). Assume the two substances don't react with each other. The mixture of 4-toluic acid and 4-bromoaniline is dissolved in ether. You MAY need the following information: The pKa of HCl is -7; pKa of carbonic acid is 6.52 and the pKa of water is 15.
a) Why would using either sodium bicarbonate or sodium hydroxide be able to extract 4-toluic acid into the aqueous layer? (Give reasons for both)
b) What would the name of the species in the aqueous layer be when the mixture mentioned above is extracted with either sodium hydroxide or sodium bicarbonate?
c) If you react the mixture above with aqueous HCl first, why would it only extract the 4-bromoaniline into the aqueous layer?
A solution is made by dissolving 0.100 mols of NaOCl in 100.0 mL of water. The Ka of hypochlorous acid (HClO) is 3.0*10^-8 at 25.0 degrees C.
calculate the air velocity necessary to suspend 1.5 cm (screened) particles of shredded aluminum; ps = 2.70 g/cm^3 and r= 0.0012 g/cm^3.
How many grams of potassium chlorate decompose to potassium chloride and 510. mL of O2 at 128°C and 652 torr?
The iron (55.847 g/mol) in a 700.0 mL sample of a natural water was determined by precipitation of the cation as hydrated Fe2O3. The precipitate was filtered
In an acid-base titration experiment, 50.00 mL of a 0.0500 M solution of acetic acid (ka=1.75 x 10^-5) was titrated with a 0.0500 M solution of NaOH at 25 degree C
What was the volume of the aluminum cylinder in cm3? The mass of the aluminum cylinder was determined to be 30.1 grams. What is the density of the aluminum?
a chemical reaction produces 653,550 kJ of energy as heat in 142.3 mins. Calculate the rate of energy transfer in kilojoules per minute.
At 0.0oC, if the volume of air is 2.6 mL and the pressure of the atmosphere that day is 815 mmHg, what is the number of moles of air?
a mass of 2.50 g of hydrated copper sulfate is placed in a crcible and heated. on heating, 1.59 g of white anhydrous copper sulfate is left behind. determine the ratio of water to copper sulfate.
The equilibrium constant for CaCO3 dissolution in water at 25 celsius is 8.7 x 10^-9. Calculate the (G) Gibbs free energy for this process.
A compound is found to be 74.03% C, 8.70% H, and 17.27% N. The molar mass of the compound is 162.23 g/mol. Find the empirical formula and the molecular formula of the compound?
Note that in some cases, the "product" may be the result of a proton transfer reaction. Do not assume that an aqueous workup (H3O+) is performed unless it is specified
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